5-Bromo-2-(4-fluorophenyl)-7-methyl-3-methylsulfinyl-1-benzofuran
نویسندگان
چکیده
In the title compound, C(16)H(12)BrFO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent are located on opposite sides of the plane through the benzofuran fragment. The 4-fluoro-phenyl ring is rotated out of the benzofuran plane, as indicated by the dihedral angle of 16.17 (5)°. The crystal structure exhibits an inter-molecular C-H⋯O hydrogen bond and a Br⋯O halogen inter-action [3.112 (2) Å].
منابع مشابه
5-Bromo-2-(4-fluorophenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C(15)H(10)BrFO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent are located on opposite sides of the plane through the benzofuran fragment. The 4-fluoro-phenyl ring is rotated out of the benzofuran plane, as indicated by a dihedral angle of 26.23 (5)°. The crystal structure is stabilized by a non-classical inter-molecular C-H⋯O hydrogen bond and a B...
متن کامل5-Fluoro-2-(4-fluorophenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C(15)H(10)F(2)O(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-fluoro-phenyl ring is rotated out of the benzofuran plane by a dihedral angle of 28.09 (3)°. The crystal structure is stabilized by weak inter-molecular C-H⋯O and C-H⋯F hydrogen bonds.
متن کامل2-(4-Fluorophenyl)-5-iodo-7-methyl-3-methylsulfinyl-1-benzofuran
In the title compound, C(16)H(12)FIO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-fluoro-phenyl ring is rotated slightly out of the benzofuran plane, as indicated by the dihedral angle of 7.43 (6)°. In the crystal structure, pairs of short I⋯O [3.074 (2) Å] contacts link the mol-ecules into cent...
متن کامل2-(4-Fluorophenyl)-3-methylsulfinyl-5-phenyl-1-benzofuran
In the title mol-ecule, C(21)H(15)FO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent are situated on the opposite sides of the plane through the benzofuran fragment. The benzofuran ring plane makes dihedral angles of 28.63 (6) and 31.55 (5)° with the 4-fluoro-phenyl and phenyl rings, respectively. Weak C-H⋯F and C-H⋯O hydrogen bonds and inter-molecular C-H⋯π inter-action...
متن کامل5-Bromo-2-(4-methylphenyl)-3-methylsulfinyl-1-benzofuran
In the title compound, C16H13BrO2S, the 4-methyl-phenyl ring makes a dihedral angle of 29.58 (7)° with the mean plane [r.m.s. deviation = 0.007 (2) Å] of the benzofuran fragment. In the crystal, the molecules are linked by pairs of C-H⋯O hydrogen bonds into centrosymmetric dimers.
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